Hard Chrome Plating vs. HVOF Process
Why the Technology?
- Used for fluid power hydraulic repairs in cylinders and corner groups
- Provides long-term robust repair for hydraulic and fluid power components
- Cutting edge environmentally friendly technology
- Provides a safe working environment for associates to do repairs
Hard Chrome Plating
- Chrome Discovered 1798, first successful electrolytic plating 1856, commercial utilization late 1920’s
- Advantages
- Resists most chemicals, oxygen, and moisture in air
- Does not tend to seize, gall, or cold weld
- Hard surface typical 69 Rc, 0.003-0.015” typical thickness
- Simple technology
- Excellent wear resistance
- Historically relatively inexpensive
- Issues with hard chrome plating
- The process produces large amounts of hydrogen gas in the gas bubbles burst throwing hexavalent chrome solution into the air as fine mist. Hexavalent chrome is a know carcinogen.
- The process produces large volumes of toxic waste.
- EPA and OSHA have mandated more stringent stack emission levels and lowering of permissible exposure limits for workers.
- This results in increased costs and business risks.
Alternatives to Hard Chrome Plating Sought
- The Hard Chrome Alternatives Team (HCAT) formed during the 1990’s
- HCAT is a bi-national team comprised of Dept of Defense, US airlines, Canadian military and airline industries, support manufacturers
- Methods evaluated were Arc Spraying, Plasma Spraying, Flame Spraying, and High Velocity Oxy-Fuel (HVOF)
The Best Alternative
- The best clean alternative method determined by HCAT was HVOF thermal spray for Hydraulic
Actuators (Cylinder Rods) - The HVOF process utilizes a material in powder form injected into a flame of supersonic gas
- The material softens in the flame and forms a dense coating on the substrate.
HVOF
- The fuel for the flame is a gas such as hydrogen, acetylene, propylene, or a liquid such as kerosene
- The coating material is usually a metal alloy such as chrome carbide
- Typical deposit coating layers range from 0.003-0.015” in thickness
HVOF Spray Gun Cutaway
HVOF
- The two primary companies that make the HVOF spray equipment are Sulzer-Metcoand Praxair/TAFA
| | Sulzer-Metco | Praxair/TAFA |
| Fuel | Hydrogen, Propane, Propylene, Natural Gas | Kerosene |
| Carrier Gas | Nitrogen | Nitorgen, Argon |
| Oxidizer | Oxygen | Oxygen |
| Particle Velocity | Mach1 | Mach2+ (3300-3900 feet/second) |
| Temperature | 5000 F | 5600 F |
HVOF
- The part to be coated must have chrome removed by stripping electrolytically or grinding
- If the surface has been previously HVOF coated, the surface must be ground to remove any
- imperfections
- Any area not to be coated must be masked off
- The surface to be coated must be thoroughly grit blasted using aluminum oxide material-36 grit-the prepared
surface must be kept clean from this point on - The work piece is put into the HVOF thermal spray cabinet.
- During the spray process the work piece rotates at 300 surface feet per minute
- Each pass applies 0.001”of coating
- The work piece temperature is not allowed to exceed 350 F, the spray process can be stopped and started to
limit this temperature HVOF - Final surface finishing requires use of either diamond belts or diamond grinding wheels
- It is necessary to not only grind but also
superfinish - The finished surface is measured and documented
- The bond strength is >10,000 PSI
Comparison of Hard Chrome Plating to HVOF
| | Hard Chrome Plating | HVOF |
| Surface Hardness | 69 Rc | 71Rc |
| Time required to coat Komatsu 830E first stage | 7 hours (0.002" per hour to get 0.007"/side) | 1 hour (12 lbs at 12 lbs/hr to get 0.007"/side) |
| Work Piece Temp | 145 F | 300-350 F |
| Post Plate H2 Relief | 275-425 F for 2-4 hours | Not required |
| Desired Surface Finish | 0.4-0.8 um 16-32 u in | 2-6 u in |
Comparison of Hard Chrome Plating to HVOF
- At the bottom of each photo is the substrate material that is being coated.
Benefits of HVOF Coatings
- High density, low porosity
- Improved corrosion barrier
- Higher hardness ratings
- Improved wear resistance
- High bond strength
- Thick coatings
- Smoother as-sprayed surfaces
Summation
- Hard chrome has the advantage that it is a single material and deposition method that can be used for a wide variety of applications
- HVOF is a single technology, with a wide variety of materials that can be used to achieve the right combination of properties for many purposes.
Hazardous Environment Changes
- Provides a safer work environment for our people
- 80% reduction in hazardous waste
- Waste produced is considerably less hazardous than Hard Chrome Plating
HVOF Spray Booth with Stage Being Sprayed - Pre-heat Pass
HVOF Spray Booth with Stage Being Sprayed. Actual Spray Pattern
Grinder/Super Finisher